Gibbs Free Energy Calculator

CHEMISTRY THERMODYNAMICS ΔG = ΔH−TΔS SPONTANEITY
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Gibbs free energy calculator (ΔG = ΔH − TΔS) — enter three of ΔG, ΔH, temperature and ΔS, solve for the fourth and see whether the reaction is spontaneous. Curriculum-aligned.

RT-SCI-027 · Science

Gibbs Free Energy Calculator

Curriculum
ΔG = ΔH − T · ΔS

Enter any three values and leave the fourth blank — the calculator solves for it. ΔG and ΔH are in kJ/mol, ΔS in J/(mol·K), temperature in K (or °C).

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Tool information
Curriculum
English (global) — Cambridge International + IB
Built against
Cambridge International A-Level Chemistry 9701 + IB Diploma (2023–2025) — Gibbs Free Energy
Unit system
SI primary; US/imperial readout below
First published
2 Jun 2026
Last updated
2 Jun 2026

How to Use the Gibbs Free Energy Calculator

Pick your curriculum

Use the curriculum pills above to match your syllabus (Cambridge A-Level/IB, 高考 or STPM). Terminology and the whole page follow your selection.

Enter three values

Type three of ΔG, ΔH, temperature and ΔS — leave the one you want to find blank. Watch out: ΔH is usually in kJ/mol but ΔS in J/(mol·K).

Read the result

The calculator solves for the blank quantity and tells you whether the reaction is spontaneous (ΔG < 0), at equilibrium, or non-spontaneous.

Check against your syllabus

The Tool Information block shows exactly which syllabus this is built against. Spot something off? Use the feedback button.

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Gibbs Free Energy, in Your Curriculum's Words

Gibbs Free Energy (ΔG = ΔH − TΔS)

ΔG = ΔH − TΔS

Example: A reaction has ΔH = −50 kJ/mol and ΔS = +100 J/(mol·K) at 298 K. Find ΔG and decide whether it is spontaneous.

Given: ΔH = −50 000 J/mol, T = 298 K, ΔS = 100 J/(mol·K). Using ΔG = ΔH − TΔS:

ΔG = −50 000 − (298 × 100) = −79 800 J/mol = −79.8 kJ/mol → spontaneous

Gibbs free energy combines enthalpy and entropy to predict whether a reaction happens spontaneously: ΔG = ΔH − TΔS. ΔH is the enthalpy change (heat), ΔS the entropy change (disorder), and T the absolute temperature in kelvin. If ΔG is negative the reaction is spontaneous at that temperature; if positive it is non-spontaneous; if zero the system is at equilibrium.

A common mistake is mixing units: ΔH and ΔG are usually given in kJ/mol, but ΔS in J/(mol·K) — a factor of 1000 apart. This calculator converts everything to consistent units for you. Because the TΔS term depends on temperature, some reactions switch from non-spontaneous to spontaneous when heated. All calculation happens in your browser — nothing is uploaded.

Gibbs free energy is the final arbiter of spontaneity — it combines energy and disorder into a single number.

10 Facts About Gibbs Free Energy

01

Gibbs free energy: ΔG = ΔH − TΔS.

02

ΔG < 0 means the reaction is spontaneous.

03

ΔG = 0 means the system is at equilibrium.

04

ΔH is usually in kJ/mol; ΔS in J/(mol·K).

05

The TΔS term depends on temperature.

06

Exothermic reactions have a negative ΔH.

07

Entropy measures the disorder of a system.

08

Some reactions are spontaneous only when heated.

09

Named after Josiah Willard Gibbs.

10

This calculator runs in your browser — your working stays private.

Frequently Asked Questions

  • ΔG = ΔH − TΔS — the change in Gibbs free energy equals the enthalpy change minus the absolute temperature times the entropy change. The calculator can solve for any one of the four quantities when the other three are known, and also tells you the spontaneity of the reaction.
  • If ΔG is negative, the reaction is spontaneous (it proceeds on its own) at that temperature. If positive, it is non-spontaneous and needs energy to drive it. If ΔG is exactly zero, the system is at equilibrium and no net change occurs.
  • By convention ΔH and ΔG are given in kilojoules per mole (kJ/mol) because the values are large, while ΔS is given in joules per mole per kelvin (J/(mol·K)). This factor-of-1000 difference is a common source of error, so the calculator converts everything to consistent units before calculating.
  • Because T in ΔG = ΔH − TΔS is an absolute temperature. Using degrees Celsius directly gives the wrong TΔS term. If you enter °C, the calculator converts it to kelvin by adding 273.15.
  • Yes. Because the TΔS term depends on temperature, a reaction with both ΔH and ΔS positive becomes spontaneous only when the temperature is high enough, while one with both negative is spontaneous only at low temperatures.
  • The chemistry — ΔG = ΔH − TΔS — is identical worldwide. What changes is the terminology; "Gibbs free energy" is 吉布斯自由能 in Chinese. The calculated value is the same.
  • The Tool Information block lists the exact syllabus for your selected curriculum (e.g. STPM Kimia or Cambridge A-Level 9701). It is a study aid, not a substitute for your official syllabus or teacher.
  • No. Every calculation runs in your browser; nothing you type is uploaded. It works offline once the page has loaded.
  • Completely free, no account or usage limit. It runs entirely in your browser and collects no data.

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